No, charging is a condition, ProfileMatic can not control whether the device is charging or not - it can only detect when the device is charging or not. So, you can make different actions based on whether your N9 is charging or not.

On somewhat related note: I'm not at all sure if the "Not charging" condition is in anyway useful, but people always surprise me how they want to use ProfileMatic. So I included it as it came "free" with the charging condition.