Hmmm... not sure if this will work, but it's worth a try. Open terminal, gainroot, and run:
If that doesn't work, make sure both your memory cards are in. It seems that gpodder is trying to copy a couple files from /media/mmc2/gpodder to /home/user/.config/gpodder, but this isn't working. However, the error isn't very specific on WHAT isn't working about this... Just see if you have a /media/mmc2/gpodder directory